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<center><b> Thermodynamics : The Study of the Flow of Heat / Energy</b></center> <br> Chapters in Zumdahl, Chapter 6 (except Section 6.5) and Chapter 16 (Section 16.7-16.9)<br> Pg. <br> <u>General Information and Review</u><br> *Print out and explain [http://tmcleod.org/cgi-bin/chem1/wiki.cgi?Overview_Of_Three_Laws_Of_Thermodynamics 1st Year's 3 Laws of Thermodynamics] *[[AP - Major Concepts in Thermodynamics] (nothing in it right now, 9/30/15} *[http://www.tmcleod.org/AP/APThermo/APThermoIntro.pdf Zumdahl Notes on Internal Energy and Thermo Intro in Chapter 6] (Thermo Intro and Internal Energy notes) *HW (in Zumdahl Pg230), #21, 23, and 25. **need to use 101.3J / (L-atm) when using w = -PΔV so that units will cancel. ** you get that number/unit when you divide 8.314 J / (mole K) by 0.08206 L-atm / (mole K ). <u><b>Enthalpy </b></u>[[Enthalpy]]<br> *[http://tmcleod.org/cgi-bin/chem1/wiki.cgi?Notes_On_Video_Of_Enthalpy_And_Calorimetry 1st Year's Enthalpy Videos] *[http://www.tmcleod.org/AP/APThermo/APEnthalpyNotes.pdf Zumdahl Notes for Enthalpy Intro in Chapter 6] *Calculating Enthalpy change by:<br> **Calorimetry Equations: ***Non-phase change (system does not change phase): deltaH = (m)(deltaT)(c), where c = specific heat capacity (H<sub>2</sub>O is 1.00cal/(g-degC) or 4.18 J/(g-degC) ). There are variation on this equation where the m and c are changed but the importance thing is that units cancel. ****See [http://tmcleod.org/cgi-bin/chem1/wiki.cgi?Notes_On_Heat_Calculations 1st Year's Notes for Non-phase Change Heat Calculation Notes] ***Phase change Equation: deltaH = (m or other) (Phase change Enthalpy change) ****Big thing here is no deltaT (since in a phase change temperature does not change) and that the Phase change Enthalpy change term has some units as (m or other). ****There are various names for Phase change Enthalpy change include Molar Heat of Vaporization, Heat of Condensation, etc. **Hess' Law : [http://www.tmcleod.org/AP/APThermo/EnthalpyHessLawCalculationExample.pdf Example of Hess' Law Calculations] **Standard Enthalpy of Formation: [http://www.tmcleod.org/AP/APThermo/StandardEnthalpyFormationCalculationExample.pdf Example of Standard Enthalpy of Formation Calculations] <br> <u>Entropy and Gibbs Free Energy</u><br> *[[Gibbs Free Energy]] *Watch [https://www.youtube.com/watch?v=ZsY4WcQOrfk Crash Course Video on Entropy (but also Gibbs Free Energy)]<br> * ------<br> *[http://www.bozemanscience.com/ap-chem-053-net-energy-change Video Notes from Bozeman Science AP Chem on Enthalpy of Reaction including Hess Law]] *Day One : Introduction, [http://wine1.sb.fsu.edu/chm1045/notes/Energy/Enthalpy/Energy02.htm Enthalpy], [http://wine1.sb.fsu.edu/chm1045/notes/Energy/Calorim/Energy03.htm Calorimetry], and Hess' Law *Day Two : Hess' Law Lab and StandardHeatofFormation *Day Three : [[Entropy]] **[[Temperature of Phase Change calculation]] *Day 4 : SolubilityQuiz1 and GibbsFreeEnergy *[http://www.chemcool.com/regents/kineticsequilibrium/aim4.htm Good website for potential energy diagrams] *[http://www.tmcleod.org/AP/APThermo/APEnthalpyNotes.pdf Zumdahl Notes for Enthalpy Intro in Chapter 6]] *[http://www.tmcleod.org/AP/APThermo/APThermoIntro.pdf Zumdahl Notes on Internal Energy and Thermo Intro in Chapter 6]] *[http://www.tmcleod.org/AP/APThermo/StandardEnthalpyFormationCalculationExample.pdf Example of Standard Enthalpy of Formation Calculations] *[http://www.tmcleod.org/AP/APThermo/EnthalpyHessLawCalculationExample.pdf Example of Hess' Law Calculations] <u>2019-2020 Information</u><br> *[https://www.learner.org/series/chemistry-challenges-and-solutions/the-metallic-world-electrochemistry-and-coordination-compounds/ Anneberg Challenges Video Series Unit 11- The Metallic World: Electrochemistry and Coordination Compounds]<br> <br> *[https://www.learner.org/series/chemistry-challenges-and-solutions/equilibrium-and-advanced-thermodynamics-balance-in-chemical-reactions/ Anneberg Challenges Video Series Unit 9 - Equilibrium and Advanced Thermodynamics] <br>
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