a. Adding more reactant/products
b. Changing Temperature (really means increase Energy).
c. Pressure change (really means number of gas particles)
d. Add a catalysts
FYI, only substances or attributes that are found in the reversible reaction can stress the equilibrium system (shift the equilibrium).
Example
Stress: Adding product (increasing concentration of products)
How rxn tries to remove stress: Consume or decreasing concentration of product
Comment: Since the stress is added product, the system will try to consume the product to get back to original equilibrium (amount of product)
Circle: Make more product or more reactant (fill in for pressure changes)__________________
Comment: since I am consuming product, I am making more reactant
Circle: Favoring: Forward rxn or Backward rxn: (fill in for temperature changes) _____________
Comment: Favoring reaction means that overall that reaction is used more than the other reaction. Remember since this is equilibrium, both the forward and backward reaction occurs, but in this case overall the backward reaction was done more than the forward reaction
Circle: Shift Equilibrium to: Left(more reactant) or Right (more product)
Comment: Since the new equilibrium position has more reactant than the original equilibrium position, we say the equilibrium is shifted to the Left (side pointing to the reactant).
Example
Stress: Decreasing Temperature (decreasing, consuming or removing Energy
How rxn tries to remove stress:Making Energy (Increasing Temperature)
Comment: Since the stress is decreasing Temperature or removing Energy, the reaction will want to make Energy (to increase Temperature) so the Energy should be the "product".
Circle: Make more product or more reactant (fill in for pressure changes)__________________
Comment: Since reaction wants to make Energy, Energy should be a "product" so it is the product in the forward reaction which we call the product.
Circle: Favoring: Forward rxn or Backward rxn: (fill in for temperature changes): Forward reaction is the Exothermic reaction
Comment: Since we want to make Energy, the forward reaction (which is Exothermic) will occur (overall) more than the reverse reaction.
Circle: Shift Equilibrium to: Left(more reactant) or Right (more product)
Comment: Since we want to make more Energy in the new equilibrium position than the original equilibrium position, the other products will be in greater amount also.
Comment: In this concept, you can equate pressure of gas (does not work for liquid or solids since they are incompressible) to number of particles per volume. So if you decrease pressure, you are reducing the number of particles per volume (i.e. removing particles).
Reason why Pressure = Number of particles: As you know, only attributes or substance in the reversible reaction shift equilibrium and there is no pressure term in the reaction. However, there are number of particles of each species of reactant and product in the form of coefficients.
Example
Stress: Decreasing Pressure (Decreasing/removing/consuming number of particle
How rxn tries to remove stress: Increase Pressure (Increase/make particle
Circle: Make more product or more reactant (fill in for pressure changes): 2 product particles --> 4 reactant particles
Comment: Remember that the system can only 2 things to get rid of the stress, run the forward reaction or run the backward reaction. (Of course, you know that both reaction will occur before you reach equilibrium but "run" means overall which reaction occurs more). In this reaction, there are 4 reactant particles and 2 product particle (you only consider substances in gas phase). So the forward reaction decreases number of particle since 4 reactant particles become 2 product particles and the backward reaction increases number of particles since 2 product particles become 4 reactant particles. In this case, the system wants to increase particles so you write, "2 product particles --> 4 reactant particles" thereby making more reactants.
Circle: Favoring: Forward rxn or Backward rxn: (fill in for temperature changes) _____________
Circle: Shift Equilibrium to: Left(more reactant) or Right (more product)
Note: What would happen to the above if the number of reactant particles and number of product particles are the same.
Answer: No affect on equilibrium.
So you fill out stress portion and then explain in How rxn tries to remove stress portion that #.
A Major attributes of Equilibrium is that it does not care about time ( it is time independent). So Catalysts DO NOT SHIFT THE EQUILIBRIUM.
Example
Stress: Adding a catalyst
Comment: For Haber process, there have been several catalysts and most are iron containing compound
How rxn tries to remove stress:Catalysts do not affect Equilibrium
Circle: Make more product or more reactant (fill in for pressure changes): N/A
Circle: Favoring: Forward rxn or Backward rxn: (fill in for temperature changes): N/A
Circle: Shift Equilibrium to: Left(more reactant) or Right (more product): N/A
Comment: So after stating in the "How rxn tries to remove stress" line that catalysts do not affect equilibrium, the rest of the "answers" you fill in as N/A (even the one you are circling).