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<center><b>2005 - 2006 <nowiki>AP</nowiki> Homework</b></center> <br> Tues 1/3 Due: Wed 1/4<br> *Do Pg282 #63 a is standard heat of formation and b is Hess' Law *Do Pg282 #74 (you are assuming in heat of combustion that the coefficient in front of acteylene in the combustion reaction is one). *<b>Please do each question above on a separate sheet of paper</b> *Read and take notes on Section 16.1-16.2 16.5 and then 16.3 (please read in this order and more than one time). <b>Remember, this is Thermodynamics, it is not a novel and will take 2 or 3 times to read to understand.</b> ------------------------- <u><b>Christmas Vacation Homework</b></u><br> <b>General Notes</b><br> *Read and take notes on Ch6 (Pg239-265 and Pg273-275(Heat of Combustion)) *For these pages, for general, print out [http://www.tmcleod.org/AP/0506zumch6thermochemistry.doc Zumdahl Chapter 6 General Notes] <b>Specific notes</b> **Introduction and Internal Energy (see above notes) **[http://wine1.sb.fsu.edu/chm1045/notes/Energy/Enthalpy/Energy02.htm Enthalpy] **[http://wine1.sb.fsu.edu/chm1045/notes/Energy/Calorim/Energy03.htm Calorimetry] **StandardHeatofFormation <b>Homework (homework relates to reading/notes above)</b><br> **Pg280 #21a&c,27 **PG280 #33,35,43 **Pg280 #55 **Pg280 #61,67,73 ------------------------- Fri 12/16 Due: Mon 12/19 <b>(Review for next Test)</b><br> *Solubility questions Pg770 #102,125 *Electrochemistry Pg.863 #35(also sketch cells and give all relevant info),52,80,86(also write half cell reaction at each electrode) *Bring in a piece of metal or metal fashioned into some way (i.e. ring, etc) and we will try to plate some metal on it. Tues 12/13 Due: Thurs 12/15<br> *Pg863 #15d,16d, 49(look at your standard reduction potential table as you do problem) *Pg 864 #25a & 27 , 29b *Read Section 17.7 (look at Sample Exercise 17.9 (Pg850) <br> Mon 12/12 Due: Tues 12/13<br> *Read and take notes on Section 17.1-17.2 *I decided to give handout in class (too hard to put on website) *Find handout on Predicting chemical reactions: redox reactions, lists oxidizing agents and reducing agent. Please compare to the Standard Reduction Potential tables on Pg827 and A26 (in back of book). <br> Thurs 12/8 Due: Mon 12/12<br> *Read and take notes on Section 15.7 *Read and highlight/notes on #2 page(s) of package I gave out last class for solubility *Pg770 #97,99,101 (Look at sample Problems in section for help) Wed 12/7 Due: Thurs 12/8<br> *study for Acid Base II test Tues 12/6 Due: Wed 12/7<br> *Read handout package #1 and Section 15.6 *Do all #1 question from package Fri 12/2 Due: Tues 12/6<br> *Do [[AP Question Acid/Base]] *Answers to <nowiki>AP Question from class</nowiki> **a. In class **pH = 2.93 **pH=4.77 **<nowiki>[OH</nowiki>]<sup>1-</sup> = 3.5E-6M **pH=8.54 Thurs 12/1 Due: Fri 12/2<br> *Pg 770 #55,69,71(only do Ex59 part), 116(part a, optimal=most neutralizing power) Tues 11/29 Due: Thurs 12/1 * Read the handout on pH indicators *Do Pg 770 #63(only 0.0ml,8.0ml, 12.5ml, 25.0ml, 28.0ml of <nowiki>HCl</nowiki>), 65 Wed 11/23 Due: Mon 11/28<br> *Pg770 39, 44,59 Mon 11/21 Due: Wed 11/23<br> *Calculate the mass of sodium acetate you need to add to 50.0ml of <b>0.10M </b>acetic acid to have the solution be at a pH=4.00 (called a pH 4 buffer). *Calculate the mass of sodium acetate you need to add to 50.0ml of <b>1.0M</b> acetic acid to have the solution be at a pH=4.00 (called a pH 4 buffer). **Use Henderson - Hasselbalch (<nowiki>H-H</nowiki>) equation. **Remember the recipical of a log is 10<sup>x</sup>. Fri 11/18 Due: 11/21<br> *Read and take notes on Section 15.1 - 15.3 (Common ion effect, buffers, and buffer capacity) *Read and take notes on Section 15.4 (Pg728-732) <b>Test on <nowiki>Acid/BaseI</nowiki> on Wed 11/16</b><br> Tues 11/15 Due: Wed 11/16<br> *Study for Acid Base I test Mon 11/14 Due: Tues 11/15<br> *Pg700 65,69,100 *Complete calculation for [[pH reading of strong and weak acid/base and salts Lab]] Tues 11/8 Due: Wed 11/9<br> *Pg700 #107,109,111,115 Fri 11/7 Due: Tues 11/8<br> *All from last day homework *Read and take notes (supplement handout) Section 14.8 *Pg700 #55,89 Thurs 11/3 Due: Mon 11/7<br> *Do Pg700 #28a,47,51,81b&c,82c *Read and take notes on Section 14.5 (except mixtures & percent dissocation), all of Section 14.6, and Section 14.12 Wed 11/2 Due: thurs 11/3 <br> *Study for Ch13 test Mon 10/31 Due: Wed 11/2<br> *Print out and read [http://www.tmcleod.org/AP/ELECTROLYTES.doc Electrolytes handout] *Read and take notes on Section 14.1 - 14.4 and 14.6 (up to Pg 673) Fri 10/28 Due: Mon 10/31<br> *Do Pg645 #82 *Complete redo Ch4 test questions Wed 10/26 Due:Fri 10/28<br> *Get ready for lab test *Work on redoing Ch4 test. *Quantitative analysis lab: <br> <nowiki>KHS</nowiki> - K H S O<sub>4</sub><br> <nowiki>KHT</nowiki> - K H C<sub>4</sub> H<sub>4</sub> O<sub>6</sub><br> <nowiki>KHP</nowiki> - K H C<sub>8</sub> H<sub>4</sub> O<sub>4</sub><br> Tues 10/25 Due: Wed 10/26<br> *Get all homework for term together for Homework Test *Get labs into lab notebook as formal lab. Come with questions. (lab test is on Fri, next class) Mon 10/24 Due: Tues 10/25<br> *Complete Equilibrium lab questions and calculations Thurs 10/20 Due: Mon 10/24<br> *<b>Remember Mon we are celebrating Mole Day, so bring in a mole (6) of something. Please, Please.</b> *Do Pg 640 #61,58 (answer to #58 is [H<sub>2</sub>S] = 9.4X10<sup>-3</sup>M) *Complete all the net ionic reactions for the Qualitative analysis lab *Start working on [[APQuestion2]] (Due Wed) Wed 10/19 Due: Thurs 10/20<br> *Read and take notes on Section 13.7 (supplement handout notes with reading notes) *On a separate sheet of paper <b>in your notes</b>, write out your steps for solving equilibrium problems (in your own words not books) *Do Pg642 #47, 55 *work on Qualitative lab <br> Mon 10/17 Due: Wed 10/19<br> *Work on Qualitative Analysis Lab *Pg640 #21,46,49 Tues 10/11 Due: Thurs 10/13<br> *Pg 232 #27,49,61,63(read Pg205-207 for helpin problem 63). Make sure to look at GasLaws for notes on Gas Laws.<br> *Read & take notes on Section 13.1-13.2 and (print out) [http://www.tmcleod.org/cgi-bin/chem1/wiki.cgi?Equilibrium_Notes_1 Equilibrium Notes 1 from 1st year] & [http://www.tmcleod.org/cgi-bin/chem1/wiki.cgi?Equilibrium_Notes_2 Equilibrium Notes 2 from 1st year]<br> <b>We have moved Ch 4 test back to next Tues (1st class after the long weekend)</b><br> Thurs 10/6 Due:Tues 10/11<br> *Study for Ch4 test *Start working on Pg 232 #27,49,61,63(read Pg205-207 for helpin problem 63). Make sure to look at GasLaws for notes on Gas Laws.<br><b>These problems will be due the class after the test.</b> <br> Tues 10/4 Thurs 10/6<br> *Since we have changed the test date, we will go on to the next subject, Gas Laws. We will only spend 1/2 day now on this concept. We will deal with it later also. *So I am sending you back to my 1st year webpage so that you can print out and review all the relevant concepts for gas law. So look at GasLaws. <b>Don't be fooled, there is a boat load of reading/reviewing here.</b> Make sure you go to the webpage on Animation (mhhe site) of Gas Laws and Avogadro's Hypothesis. <br> Mon 10/3 Due: 10/4<br> *Pg182 #39,77,78(inspection=by oxidation number), 92(c,d) Wed 9/28 Due: Fri 9/30<br> *Memorize solubility rules *Read Section 4.8 *Pg 182 #69,49,51 *1st year book Pg618 #16 <b>[[APQuestion1]] Due Wed 9/28</b><br> Tues 9/27 Due:Wed 9/28<br> *Pg183 #59a,c,e & 61a&b *Finish [[APQuestion1]] Fri 9/23 Due: Tues 9/27<br> *Do Pg181 #37 (stoichiometry of precipitation reactions) *Do Pg181 #57a-d (oxidation number & redox reaction) *Read & take notes on Section 4.10 Balancing <nowiki>Oxidation-Reduction</nowiki> reaction by half-cell method. (these are your notes for concept) *Work on memorizing solubility rules Wed 9/21 Due: Thurs 9/22 *Read and take notes on Section 4.1 - 4.7 *[http://www.tmcleod.org/AP/0506apzumch4notes.doc Help Notes for Section 4.1 - 4.6] *Do Pg.180 #12, 15, 18, 20a&b *(expect quiz on molarity after questions) Fri 9/16 Mon 9/19 (<b>Test:Wed 9/21</b>) *study for test Wed 9/14 Due: Fri 9/16<br> *Quiz on NamingCompounds *Complete HomeworkSet5 Tues 9/13 Due: Wed 9/14<br> *Work on HomeworkSet5 Wed 9/7 Due: Thurs 9/8<br> *Quiz on CationTable *SummerWork due in my mailbox by Fri 9/9 *Read and print out CombustionAnalysis <br> Mon 9/12 Due: Tues 9/13<br> *Quiz on Polyatomic Ions
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